The hydrolysis of CINO3 on sub micron liquid sulphuric acid aerosols
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Date
1998
Authors
Ball, S.
Fried, A.
Mozurkewich, M.
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Publisher
AGU
Abstract
The reactive uptake of ClONO2 on liquid sulfuric acid has been measured for size‐selected, sub‐micron aerosol in the composition range 36–54% H2SO4 by weight at ≈ 250 K. A comparison with results from studies employing bulk surfaces at similar temperatures and compositions shows no evidence for a dependence of the reaction probability, γ, on size. We use this observation to estimate an upper limit to the diffuso‐reactive length of 26 nm for the ClONO2 + H2O reaction on 43 weight % aerosol at 248 K. But, the present values of γ are consistently lower than bulk values observed at lower temperatures and similar composition, suggesting that γ is temperature dependent.
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Geophys. Res. Letters, 25, 3339-3343