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The Use of Isothermal Gas Chromatography for the Determination of Adsorptionenthalpies and entropies of Inorganic Halides at High Temperatures

The Use of Isothermal Gas Chromatography for the Determination of Adsorptionenthalpies and entropies of Inorganic Halides at High Temperatures

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Title: The Use of Isothermal Gas Chromatography for the Determination of Adsorptionenthalpies and entropies of Inorganic Halides at High Temperatures
Author: Rudolph, J.
Bachmann, K.
Abstract: Gas chromatography was used to determine the adsorption enthalpies and
entropies of inorganic chlorides on sslid non-porous adsorhents (silica, alkali
metal chlorides, graphite, etc.) at high temperatures (65th1100°K). The results
demonstrate that gas chromatography is also a useful method for investigations in
the field of inorganic chemistry. The adsorption enthalpies and entropies (or rather,
chemisorption enthdpies and entropies) indicate that the adsorption (or chemisorption
proCess>i nvolves complex formation between the adsorbed molecules and
the adsorbent (coordinative by bonded surface complex).
Type: Article
Rights: http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TG8-453BY0F-8N&_user=866177&_coverDate=01%2F18%2F1980&_rdoc=1&_fmt=high&_orig=search&_sort=d&_docanchor=&view=c&_searchStrId=1193840276&_rerunOrigin=google&_acct=C000045519&_version=1&_urlVersion=0&_userid=866177&md5=dd1832363a52ed809f405b1f6e2a2aef
http://www.sciencedirect.com/science/journal/00219673
URI: http://hdl.handle.net/10315/2934
Citation: J. Chromatogr., 187, 319-329
Date: 1980

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